A. Kawabata et al., HOT ISOSTATIC PRESSING AND CHARACTERIZATION OF SOL-GEL-DERIVED CHROMIUM(III) OXIDE, Journal of the American Ceramic Society, 78(8), 1995, pp. 2271-2273
Chromium(III) oxide (Cr2O3) crystallizes at low temperatures from an a
morphous material prepared by adding hydrazine monohydrate to an aqueo
us solution of Cr(NO3)(3). 9H(2)O. Individual particles of Cr2O3 tend
toward a hexago nal morphology above 800 degrees C. Well-densified Cr2
O3 pellets (98.8% of theoretical density) have been fabricated by hot
isostatic pressing for 2 h at 1100 degrees C and 196 MPa. Their fractu
re toughness is 4.4 MPa . m(1/2). The sample annealed in air for 12 h
at 1300 degrees C exhibits a high electrical conductivity of 3.6 Ohm-1
.m(-1) at 700 degrees C.