VERSATILITY OF THE AZIDO BRIDGING LIGAND IN THE FIRST 2 EXAMPLES OF FERRO-ANTIFERROMAGNETIC ALTERNATING NICKEL(II) CHAINS

Authors
RIBAS J MONFORT M GHOSH BK SOLANS X FONTBARDIA M
Citation
J. Ribas et al., VERSATILITY OF THE AZIDO BRIDGING LIGAND IN THE FIRST 2 EXAMPLES OF FERRO-ANTIFERROMAGNETIC ALTERNATING NICKEL(II) CHAINS, Journal of the Chemical Society, Chemical Communications, (23), 1995, pp. 2375-2376
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
23
Year of publication
1995
Pages
2375 - 2376
Database
ISI
SICI code
0022-4936(1995):23<2375:VOTABL>2.0.ZU;2-I
Abstract
A one-pot reaction of Ni(ClO4)(2) . 6H(2)O, N,N-dimethylethylenediamin e (dmen) or 2-aminoethylpyridine (aep) and NaN3 affords the two [Ni(dm en)(mu-N-3)(2)](n) 1 and [Ni(aep)(mu-N-3)(2)](n) 2 chains with unprece dented alternating end-on and end-to-end bridging loops perpendicular to one another; magnetic susceptibility measurements indicate that the y are the first two ferro-antiferromagnetic alternating chains of Ni-I I.