COMPARATIVE-STUDY ON GAMMA-RADIOLYSIS AND ENERGY-TRANSFER REACTION INDUCED BY GAMMA-IRRADIATED NACL IN METHYL-ORANGE AND METHYL RED

Citation
D. Ravishankar et B. Raju, COMPARATIVE-STUDY ON GAMMA-RADIOLYSIS AND ENERGY-TRANSFER REACTION INDUCED BY GAMMA-IRRADIATED NACL IN METHYL-ORANGE AND METHYL RED, Journal of radioanalytical and nuclear chemistry, 178(2), 1994, pp. 351-357
Citations number
8
Categorie Soggetti
Chemistry Analytical","Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
ISSN journal
02365731
Volume
178
Issue
2
Year of publication
1994
Pages
351 - 357
Database
ISI
SICI code
0236-5731(1994)178:2<351:COGAER>2.0.ZU;2-W
Abstract
A comparative study on gamma-radiolysis and energy transfer reaction i nduced by gamma-irradiated sodium chloride in azo-dye indicators, viz. Methyl Orange and Methyl Red am undertaken. These indicators undergo degradation following first order kinetics, the determined rate consta nts being approximately 1.05. 10(-8) rad-1 for Methyl Orange and appro ximately 5.00 . 10(-7) rad-1 for Methyl Red, respectively. The G-value s are also determined and are found to be lower for Methyl Orange (8.6 0. 10(-6)) and higher for Methyl Red (4.05 . 10(-3)), suggesting that the former is more resistent to radiation degradation as compared to t he latter.