CHEMICAL EFFECTS OF (N, GAMMA) NUCLEAR-REACTION ON (MO6CL8)CL4

Citation
La. Fucugauchi et al., CHEMICAL EFFECTS OF (N, GAMMA) NUCLEAR-REACTION ON (MO6CL8)CL4, Journal of radioanalytical and nuclear chemistry, 178(2), 1994, pp. 437-442
Citations number
14
Categorie Soggetti
Chemistry Analytical","Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
ISSN journal
02365731
Volume
178
Issue
2
Year of publication
1994
Pages
437 - 442
Database
ISI
SICI code
0236-5731(1994)178:2<437:CEO(GN>2.0.ZU;2-M
Abstract
The chemical effects of Mo-98(n,gamma)Mo-99 reaction on molybdenum(II) chloride [(Mo6Clg)Cl4] have been studied. Retention, thermal and radi olytical annealing were determined. It was found that this molybdenum compound has low retention, a negligible tendency to thermal annealing and a virtual insensitivity to hydrolysis. For practical application in the enrichment of Mo-99 by the Shilard-Chalmers method, molybdenum( II) chloride [(Mo6Cl8)Cl4] appears to offer good prospects.