A DETAILED STUDY OF (ETA(3)-CYCLOHEXENYL)PALLADIUM SYSTEMS

Authors
MARTIN JT OSLOB JD AKERMARK B NORRBY PO
Citation
Jt. Martin et al., A DETAILED STUDY OF (ETA(3)-CYCLOHEXENYL)PALLADIUM SYSTEMS, Acta chemica Scandinavica, 49(12), 1995, pp. 888-893
Citations number
32
Categorie Soggetti
Chemistry,Biology
Journal title
Acta chemica Scandinavica → ACNP
ISSN journal
0904213X
Volume
49
Issue
12
Year of publication
1995
Pages
888 - 893
Database
ISI
SICI code
0904-213X(1995)49:12<888:ADSO(S>2.0.ZU;2-0
Abstract
The primary products from palladium(II)-assisted nucleophilic addition to 1.4-cyclohexadienes (eta(3)-cyclohexenylpalladium complexes) have been investigated by NMR spectroscopy. The chloride-bridged dimers are shown to interconvert rapidly between diastereomeric form with exchan ge of monomeric units, The boat-chair equilibrium is too fast to be fr ozen out even at - 130 degrees C, An anomalous cis addition product is shown to be formed indirectly From the normal trans product.