Q. Trancong et al., EXTREMELY SLOW REORIENTATION DYNAMICS OF MOLECULAR TRACERS IN GLASSY-POLYMERS, Journal of molecular liquids, 65-6, 1995, pp. 325-328
A new experimental method based on the polarization-selective photochr
omic reactions is proposed to monitor extremely slow reorientation dyn
amics of molecular tracers in glassy polymer matrix. The correlations
between the local relaxation processes of polymers and the reorientati
on dynamics of the tracers with different sizes are found from the exp
erimental results obtained by this method.