CHIRAL OXAZOLINYLFERROCENE-PHOSPHINE HYBRID LIGAND FOR THE ASYMMETRICHYDROSILYLATION OF KETONES

Authors
NISHIBAYASHI Y SEGAWA K OHE K UEMURA S
Citation
Y. Nishibayashi et al., CHIRAL OXAZOLINYLFERROCENE-PHOSPHINE HYBRID LIGAND FOR THE ASYMMETRICHYDROSILYLATION OF KETONES, Organometallics, 14(12), 1995, pp. 5486-5487
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
12
Year of publication
1995
Pages
5486 - 5487
Database
ISI
SICI code
0276-7333(1995)14:12<5486:COHLFT>2.0.ZU;2-M
Abstract
A neu, type of chiral oxazolinylferrocene-phosphine hybrid is a very e ffective ligand for Rh(I)-catalyzed asymmetric hydrosilylation of simp le ketones to give the corresponding sec-alcohols (91% ee) after acid hydrolysis. Similar reactions also proceed highly selectively (96% ee) by use of Ir(I) catalyst, but the configuration of the products is co mpletely reverse.