M. Niemeyer et Pp. Power, SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (LIN(SIME(3))(2)MME(3))INFINITY (M=AL,GA) - AMIDO LIGANDS ISOELECTRONIC TO THE ALKYL GROUP -C(SIME(3))(3), Organometallics, 14(12), 1995, pp. 5488-5489
The synthesis and structural characterization. of the lithium salts {L
iN(SiMe(3))(2)MMe(3)}(infinity) (M = Al (1), Ga (2)) are described. Th
e compounds are essentially isostructural and are associated into infi
nite chains that involve bridging by the lithium ion to an aluminum or
gallium methyl group of a neighboring molecule.