SYNTHESIS OF THE CATIONIC SILYLENEIRON COMPLEX [(ETA-C5H5)FE(CO)(2)=SIME(2-(ME(2)NCH(2))C6H4)]PF6 BY HYDRIDE ABSTRACTION FROM A (HYDROSILYL)IRON COMPLEX WITH PH(3)CPF(6)

Authors
KOBAYASHI H UENO K OGINO H
Citation
H. Kobayashi et al., SYNTHESIS OF THE CATIONIC SILYLENEIRON COMPLEX [(ETA-C5H5)FE(CO)(2)=SIME(2-(ME(2)NCH(2))C6H4)]PF6 BY HYDRIDE ABSTRACTION FROM A (HYDROSILYL)IRON COMPLEX WITH PH(3)CPF(6), Organometallics, 14(12), 1995, pp. 5490-5492
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
12
Year of publication
1995
Pages
5490 - 5492
Database
ISI
SICI code
0276-7333(1995)14:12<5490:SOTCSC>2.0.ZU;2-P
Abstract
A cationic intramolecular base-stabilized silyleneiron complex, (eta-C 5H5)Fe(CO)(2)=SiMe{2-(Me(2)NCH(2))C6H4}]PF6, was synthesized by hydrid e abstraction from the (hydrosilyl)iron complex (eta-C5H5)Fe(CO)(2)SiH Me{2-(Me(2)NCH(2))C6H4} with Ph(3)CPF(6). Reaction of the silylene com plex with MeOH afforded the methoxysilyl complex eta-C5H5)Fe(CO)(2)SiM eOMe{2(Me(2)N(H)CH2)C6H4}]PF6 in good yield. The molecular structures of the silylene and methoxysilyl complexes were determined by X-ray cr ystal structure analysis.