ORGANOMETALLIC COMPLEXES FOR NONLINEAR OPTICS .4. CUBIC HYPERPOLARIZABILITIES OF (CYCLOPENTADIENYL)BIS(PHOSPHINE)RUTHENIUM SIGMA-ARYLACETYLIDES

Authors
WHITTALL IR HUMPHREY MG
Citation
Ir. Whittall et Mg. Humphrey, ORGANOMETALLIC COMPLEXES FOR NONLINEAR OPTICS .4. CUBIC HYPERPOLARIZABILITIES OF (CYCLOPENTADIENYL)BIS(PHOSPHINE)RUTHENIUM SIGMA-ARYLACETYLIDES, Organometallics, 14(12), 1995, pp. 5493-5495
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
12
Year of publication
1995
Pages
5493 - 5495
Database
ISI
SICI code
0276-7333(1995)14:12<5493:OCFNO.>2.0.ZU;2-C
Abstract
Third-order molecular optical nonlinearities of a systematically varie d series of (cyclopentadienyl) bis(phosphine)ruthenium arylacetylide c omplexes have been determined by Z-scan and degenerate four-wave mixin g techniques: the influence on the nonlinear response of replacing the acetylide by a chloro ligand, varying the phosphine, extending the ac etylide chain length, or modifying the substituent at the 4-position o f the arylacetylide has been studied.