FACILE RETRO-[1,4]-BROOK REARRANGEMENT OF A [(2-SILOXYCYCLOPENTYL)METHYL]LITHIUM SPECIES

Authors
JIANG XL BAILEY WF
Citation
Xl. Jiang et Wf. Bailey, FACILE RETRO-[1,4]-BROOK REARRANGEMENT OF A [(2-SILOXYCYCLOPENTYL)METHYL]LITHIUM SPECIES, Organometallics, 14(12), 1995, pp. 5704-5707
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
12
Year of publication
1995
Pages
5704 - 5707
Database
ISI
SICI code
0276-7333(1995)14:12<5704:FRROA[>2.0.ZU;2-W
Abstract
The [1,4]-O --> C migration of the TBDMS group in the [(2-(tert-butyld imethylsiloxcy)cyclopentyl)- methyl]lithium system (1 and 2) has been found to be confined to the cis-isomer (1).