I-III-VI2 compound semiconductors are important photovoltaic (PV) mate
rials with electrical and optical properties that can be tuned for opt
imum device performance. Polycrystalline thin films of ternary and mul
tinary compounds from the Cu (In, Ga) (Se, S)2 family have already yie
lded laboratory size solar cells with over 15% efficiency. Large area
PV modules with over 10% efficiency have also been demonstrated using
these materials. In this contribution we briefly review the preparatio
n techniques for thin film I-III-VI2 compounds with an emphasis on Cu(
In, Ga)Se2 and discuss certain characteristics of these films that are
important for good solar cell performance.