W. Heschel et E. Klose, ON THE SUITABILITY OF AGRICULTURAL BY-PRODUCTS FOR THE MANUFACTURE OFGRANULAR ACTIVATED CARBON, Fuel, 74(12), 1995, pp. 1786-1791
An investigation of several agricultural by-products revealed that the
ir suitability for activated carbon production is not determined by ge
neral material-specific features (elemental composition) but by type-s
pecific features. A coarse-cellular structure (as in wood). which is i
ndicated by porosities of the raw materials higher than similar to 35%
is disadvantageous. A specific change in the properties of cokes (por
osity, density, hardness) is possible by varying the conditions of pyr
olysis. By rapid heating in the pyrolysis step, for instance, macropor
ous residues are produced. Temperature and burnoff have the greatest i
nfluence on the quality of the activated carbon during the activation
step. Of the investigated materials, coconut shells yield granular act
ivated carbon of the highest quality. The following order of suitabili
ty of raw materials for activated carbon production was established: c
oconut shells > peach stones > plum stones > hazelnut shells > walnut
shells > cherry stones.