A residual fuel oil, neat and with four different additives, was teste
d using three experimental devices: a very fast pyrolyser of fuel drop
lets which produced cenospheres; a thermogravimetric analyser which ga
ve information on the reactivity of the cenospheres; and a 1.16 MW boi
ler. The additives did not modify cenosphere production in the pyrolys
er, but changed their reactivity. This reactivity change was in accord
ance with particulate reduction in the boiler and with the retention o
f the metal additive in the cenospheres. The retention of the metal de
pended on the nature of the organic part of the additive.