EXPEDITIOUS SYNTHESIS OF ENANTIOMERICALLY PURE TRANS-4,5-DIHYDROXY-2-CYCLOPENTEN-1-ONE

Authors
TOYAMA K IGUCHI S OISHI T HIRAMA M
Citation
K. Toyama et al., EXPEDITIOUS SYNTHESIS OF ENANTIOMERICALLY PURE TRANS-4,5-DIHYDROXY-2-CYCLOPENTEN-1-ONE, Synlett, (12), 1995, pp. 1243
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
12
Year of publication
1995
Database
ISI
SICI code
0936-5214(1995):12<1243:ESOEPT>2.0.ZU;2-6
Abstract
A short-step synthesis of (-)-(4R,5S)- and +)-(4S,5R)-trans-4,5-dihydr oxy-2-cyclopenten-1-one derivatives (14) has been achieved via the enz ymatic asymmetric transformations of meso-3,4,5-trans,trans-trihydroxy cyclopentene derivatives 12 and 15, respectively.