The hyperfine constants A and B for magnetic dipole and electric quadr
upole interaction in the S-9(4) ground state of unstable Eu-150(+) ion
s have been determined with high precision in an optical microwave dou
ble-resonance experiment. The ions were produced by nuclear reactions
at the ISOLDE facility at CERN, collected on a foil, reevaporated, and
stored in a Paul ion trap. Three of eight possible hyperfine transiti
ons between different F sublevels have been observed with well resolve
d Zeeman substructure in a residual magnetic field. Analysis of the tr
ansition frequencies and extensive second-order hyperfine correction y
ield values of A = 559 010 325(40) Hz, B = -926.2(3.0) kHz. A prelimin
ary value for the nuclear quadrupole moment Q (Eu-150(+)) = 1.264(23)
b has also been obtained.