Photoreflectance (PR) and Photoluminescence (PL) measurements have bee
n performed at 77 K on single crystals of CuAlxGa1-x(S0.5Se0.5)2 pente
rnary alloys grown by the iodine chemical vapor transport method. The
energies of excitons associated with uppermost valence bands have been
obtained as a function of composition, and an approximately quadratic
dependence has been found. Near-band-edge PL has been observed in the
crystal with x less-than-or-equal-to 0.77, and the PL has been discus
sed in terms of the free exciton.