We study the ordering process of GaxIn1-xP/GaAs, for lattice matched a
nd non-lattice matched samples in the Ga concentration range 0.51 < x
< 0.57. The valence band splitting and the band gap reduction are calc
ulated for partially ordered samples as a function of the Ga concentra
tion and of the long range order (LRO) parameter. Using polarized phot
oluminescence, we compare the effect of growth temperature and that of
Ga concentration on the LRO parameter. The degree of ordering depends
strongly on growth temperature, in the range 600-degrees-C to 725-deg
rees-C. On the other hand, the change in alloy composition has a minor
effect.