A new fabrication technique of GaAsP layers with a desired composition
on a GaP substrate was developed. A GaAs layer grown on a GaP substra
te by step cooling was brought into contact with Ga-As-P saturated sol
ution and kept at 795-degrees-C. This annealing process resulted the c
ompositional conversion of the GaAs layer to GaAsP. The composition of
the conversion layer could be controlled by adjusting the composition
of the Ga-As-P solution. Fairly good GaAsP layers were grown on the c
onversion layer by a consecutive slow cooling after the conversion pro
cess.