Titanium silicalite samples were prepared by two different procedures.
A titanium-free sample (silicalite-1) was also prepared. The samples
were characterized by XRD, SEM, skeletal ET-FIR and FT-Raman, UV-vis F
T-IR of hydroxy- groups and of adsorbed ammonia. The skeletal spectra
have been analyzed on the basis of a general interpretation of the vib
rational structure of tetrehedra-based silica polymorphs. This lead to
a partial modification of the traditional assignments of the skeletal
vibrations of zeolites, Framework Ti is found to be responsible for a
band near 960 cm(-1), in both IR and Raman spectra, and for a shoulde
r near 510 cm(-1) in the IR spectra, as well as for other weak perturb
ations of the silicalite spectra. The two main features have been assi
gned to the asymmetric stretching and to the rocking modes of Si-O-Ti
bridges. Framework Ti is found to act as a Lewis acid center, being ab
le to coordinate ammonia from gas-phase. Extraframework Ti is observed
in the form of anatase in samples prepared with the procedure 1 only
with Ti content above 2%, while TiO2 is found in all samples prepared
with the procedure 2. Both series of samples are active catalysts of p
henol hydroxylation by H2O2. (C) 1995 Academic Press, Inc.