Y. Gonzalez et al., DIELECTRIC-RELAXATION STUDY IN A GLASSY LOW-MOLECULAR-WEIGHT FERROELECTRIC LIQUID-CRYSTAL, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 52(6), 1995, pp. 5764-5767
The dynamics of a low-molecular-weight ferroelectric liquid crystal th
at can be frozen into a glassy state has been studied by means of broa
dband dielectric spectroscopy covering a wide time scale range from 10
(-10) s to 10(1) s. The temperature dependence of the relaxation frequ
ency of the process related to rotations around the molecular long axi
s follows the Vogel-Fulcher-Tammann law. The frequency of the Goldston
e mode, related to azimuthal fluctuations of the director, also shows
this unusual behavior. The results are discussed in the framework of d
ifferent theoretical approaches to the glass transition.