A. Altomare et al., TRIPLET AND QUARTET RELATIONSHIPS AND THE POSITIVITY POSTULATE, Acta crystallographica. Section A, Foundations of crystallography, 50, 1994, pp. 311-317
Positivity and atomicity are traditionally considered as basic conditi
ons for direct methods. While the role of atomicity is well understood
, the theoretical and practical consequences for a direct-methods proc
edure generated by the violation of the positivity criterion are not q
uite clear. Triplet and quartet relationships are analyzed in connecti
on with the positivity Postulate.