REACTIONS OF ISOMERIC 3,6-DI-TERT-BUTYL-ORTHO-BENZOQUINONES AND 3,5-DI-TERT-BUTYL-ORTHO-BENZOQUINONES WITH NH3

Authors
VOLEVA VB PROKOFEVA TI PROKOFEV AI BELOSTOTSKAYA IS KOMISSAROVA NL ERSHOV VV
Citation
Vb. Voleva et al., REACTIONS OF ISOMERIC 3,6-DI-TERT-BUTYL-ORTHO-BENZOQUINONES AND 3,5-DI-TERT-BUTYL-ORTHO-BENZOQUINONES WITH NH3, Russian chemical bulletin, 44(9), 1995, pp. 1720-1724
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
9
Year of publication
1995
Pages
1720 - 1724
Database
ISI
SICI code
1066-5285(1995)44:9<1720:ROI3A3>2.0.ZU;2-D
Abstract
The interaction of 3,6-di-tert-butyl-ortho-benzoquinone (1) and 3,5-di -tert-butyl-ortho-benzoquinone (2) with NH3 in water-alcohol medium an d with (NH4)(2)CO3 in a Solid phase has been studied. Redox processes with participation of a nucleophile of the medium take place for 1, wh ile 2 reacts with NH3 at the carbonyl group with transformation of the quinone imide. The mechanism of redox transformation of 1 has been pr oposed.