ESR STUDY OF SPIN-ADDUCTS OF BORON-CENTERED CARBORANYL RADICALS WITH FULLERENE-60 AND FULLERENE-70

Authors
TUMANSKII BL BASHILOV VV SOLODOVNIKOV SP BUBNOV NN SOKOLOV VI
Citation
Bl. Tumanskii et al., ESR STUDY OF SPIN-ADDUCTS OF BORON-CENTERED CARBORANYL RADICALS WITH FULLERENE-60 AND FULLERENE-70, Russian chemical bulletin, 44(9), 1995, pp. 1771-1772
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
9
Year of publication
1995
Pages
1771 - 1772
Database
ISI
SICI code
1066-5285(1995)44:9<1771:ESOSOB>2.0.ZU;2-R
Abstract
Spin-adducts of boron-centered radicals, derivatives of m-carboran-12, with fullerenes C-60 and C-70 have been studied by ESR spectroscopy. Constants of hyperfine splitting (HFS) of an unpaired electron with B- 10 and B-11 nuclei have been determined from the ESR spectra of C-.(60 )-B10H9C2H2 radicals. Three isomeric spin-adducts were detected with d ifferent HFS constants with B-11, and g-factors were detected in the r eaction of (B10H9C2H2)-B-. With C-70.