Shock waves are generated in thin films of glycidyl azide polymer (GAP
) by pulsed laser vaporization of a thin aluminum film. The rapidly ex
panding aluminum plasma launches a shock wave into the adjacent layer
of GAP, initiating chemical reactions. The shock velocity has been mea
sured by use of a velocity interferometer as a function of the thickne
ss of the GAP layer and the fluence of the Nd:YAG laser pulse. Shock p
ressures as high as 8 GPa have been generated in this manner. Detonati
on of thick GAP samples has been observed, providing important informa
tion about the chemical reaction rates and the thickness of the reacti
on zone. (C) 1995 American Institute of Physics.