Neutron diffraction has been used to determine the location and concen
tration of C in Nd2Fe17 and in a Si substituted alloy. The results ind
icate that two carbide phases exist. One contains nearly three C atoms
per formula unit, while the other has a much lower concentration. The
high C phase contains C only on the 9 e sites, but the low C phase ap
pears to contain C on the tetrahedral 18 g site. The changes in intera
tomic distances and cell volume are associated with the different site
occupancies. (C) 1995 American Institute of Physics.