S. Toyama et al., DESIGN AND CHARACTERIZATION OF NICKELOCENE, PT MICROPARTICLE, AND ENZYME CO-BLENDED GLUCOSE SENSOR, Denki Kagaku Oyobi Kogyo Butsuri Kagaku, 63(12), 1995, pp. 1095-1099
A remarkable effect of platinum on the operating potential of carbon p
aste (CP)based glucose sensor by taking advantage of nickelocene (Nic)
as an electron mediator is reported. The sensor output upon glucose a
ddition was the largest when the operating potential was -100 mV (vs A
g/AgCl) in the absence of platinum, whereas the maximum sensor output
was obtained at -200 mV when 10% (w/w) platinum powder was co-blended
in the mediator-containing carbon paste.