G. Etiope et S. Lombardi, EVIDENCE FOR RADON TRANSPORT BY CARRIER GAS THROUGH FAULTED CLAYS IN ITALY, Journal of radioanalytical and nuclear chemistry, 193(2), 1995, pp. 291-300
Extensive soil-gas surveys in sedimentary basins in Italy were perform
ed to study the potential of some naturally occurring gases as indicat
ors for concealed fracture zones, hydrocarbon and geothermal fluids. O
ne conclusive result is a positive correlation between anomalously hig
h values of radon and carbon dioxide in the soil-air over faults. The
correlation coefficient for 1173 gas samples is 0.41. Statistically de
rived contourlines of Rn and CO2 anomalies show similar locations, sha
pes and directions. Fairly good Rn-CO2 coupling evidence appears even
on a point-to-point analysis. Furthermore, it was recognized that the
highest Rn values are in contrast to the low Ra content of the underly
ing clayey rocks and that conventional Ru transportation mechanisms se
em to be inadequate for the clay sequences. All these facts strongly s
uggest that Rn is transported from the subsoil, through fault-linked p
athways, by carrier gases of which CO2 could be one of the major compo
nents. The theory of geogas microbubbles is a possible explanation of
the observed results. The carrier effect of ascending microbubbles can
explain both the origin of soil-gas Rn anomaly and the Rn-CO2 couplin
g phenomenon.