Pj. Dunlop et al., CHEMOMETRIC ANALYSIS OF GAS-CHROMATOGRAPHIC DATA OF OILS FROM EUCALYPTUS SPECIES, Chemometrics and intelligent laboratory systems, 30(1), 1995, pp. 59-67
Gas chromatograms (GCs) of oil extracted from Eucalyptus species have
been compared using principal components analysis (PCA), linear discri
minant analysis (LDA), and the Tanimoto distance in which the number o
f similar peaks between two species are determined. Two systems were s
tudied, a number of examples of E. camaldulensis Dehnh. (River Red Gum
) and clones of that species, and samples from two trees E. woodwardii
Maiden and E. torquata Luehm. and a number of their hybrids (E. torwo
odii).The PCA revealed natural groupings of E. camaldulensis clones an
d showed, via loading plots, that eight intensities of the 180 times s
tudied were sufficient to explain most of the variance and characteris
e each tree. The chemical species were identified by GC-mass spectrome
try as alpha-pinene, 1,8-cineole, p-cymene, terpinen-4-ol/aromadendren
e, cryptone, borneol, spathulenol, and torquatone. Each hybrid (E. tor
wood) of the trees E. woodwardii and E. torquata has a distribution of
oils that lies between those of the parents. LDA was able to define t
wo distinct groups and performed better than the Tanimoto distance in
classifying the trees.