A NEW, HIGHLY SELECTIVE, WATER-SOLUBLE RHODIUM CATALYST FOR METHYL ACRYLATE HYDROFORMYLATION

Authors
FREMY G CASTANET Y GRZYBEK R MONFLIER E MORTREUX A TRZECIAK AM ZIOLKOWSKI JJ
Citation
G. Fremy et al., A NEW, HIGHLY SELECTIVE, WATER-SOLUBLE RHODIUM CATALYST FOR METHYL ACRYLATE HYDROFORMYLATION, Journal of organometallic chemistry, 505(1), 1995, pp. 11-16
Citations number
49
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
505
Issue
1
Year of publication
1995
Pages
11 - 16
Database
ISI
SICI code
0022-328X(1995)505:1<11:ANHSWR>2.0.ZU;2-A
Abstract
Hydroformylation of methylacrylate to alpha-aldehyde can be achieved i n a two-phase system in the presence of two new water-soluble phosphin es. High yields and selectivities of alpha-aldehyde (ca. 80% with a al pha/beta ratio of 1:20) were obtained. Spectroscopic studies have been carried out and some new rhodium complexes formed in situ in catalyti c systems have been identified.