THE ALL-SODIUM SALT OF A POLYOXOANION-SUPPORTED ORGANOMETALLIC COMPLEX - SYNTHESIS AND CHARACTERIZATION OF DOT-P2W15NB3O62]CENTER-DOT-7DMSO-CENTER-DOT-5H(2)O

Authors
NOMIYA K NOZAKI C KANEKO M FINKE RG POHL M
Citation
K. Nomiya et al., THE ALL-SODIUM SALT OF A POLYOXOANION-SUPPORTED ORGANOMETALLIC COMPLEX - SYNTHESIS AND CHARACTERIZATION OF DOT-P2W15NB3O62]CENTER-DOT-7DMSO-CENTER-DOT-5H(2)O, Journal of organometallic chemistry, 505(1), 1995, pp. 23-28
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
505
Issue
1
Year of publication
1995
Pages
23 - 28
Database
ISI
SICI code
0022-328X(1995)505:1<23:TASOAP>2.0.ZU;2-H
Abstract
The preparation of Na-7[(eta(5)-C(5)Me(5))Rh . P2W15Nb3O62], a Dawson- type polyoxoanion-supported organometallic complex with air-inorganic countercations, is described. The compound was obtained in 39% yield a s an analytically pure, homogeneous yellow-orange solid by a reaction of [(eta(5)-C(5)Me(5))Rh(CH3CN)(3)](2+) with Na9P2W15Nb3O62 in a solve nt mixture of CH3CN-DMSO. Compositional characterization was accomplis hed by a complete elemental analysis, TG-DTA and GLC measurements. Str uctural characterization in solution was achieved by a combination of H-1, C-13, P-31 and W-183 NMR spectroscopy.