INSERTION OF ALKYNES INTO MOLYBDENUM-PHOSPHINE AND MOLYBDENUM-CARBON BONDS - X-RAY STRUCTURE OF THE PHOSPHONIUM-ALKYLIDENE COMPLEX )CH=C(PH)CH(2)PME(2)PH)((SC6H2PR3)-PR-I-2,4,6)(3)]

Authors
HUGHES DL MARJANI K RICHARDS RL
Citation
Dl. Hughes et al., INSERTION OF ALKYNES INTO MOLYBDENUM-PHOSPHINE AND MOLYBDENUM-CARBON BONDS - X-RAY STRUCTURE OF THE PHOSPHONIUM-ALKYLIDENE COMPLEX )CH=C(PH)CH(2)PME(2)PH)((SC6H2PR3)-PR-I-2,4,6)(3)], Journal of organometallic chemistry, 505(1), 1995, pp. 127-129
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
505
Issue
1
Year of publication
1995
Pages
127 - 129
Database
ISI
SICI code
0022-328X(1995)505:1<127:IOAIMA>2.0.ZU;2-1
Abstract
Treatment of [MoH((SC6H2Pr3)-Pr-i-2,4,6)(3)(PMe(2)Ph)(2)] with PhC=CH in tetrahydrofuran (THF) followed by MeOH gives the phosphonium-alkyli dene complex CH=C(Ph)CH(2)PMe(2)Ph)((SC6H2Pr3)-Pr-i-2,4,6)(3)], whose X-ray crystal structure has been determined.