CHEMICAL DEHYDROCHLORINATION OF POLYTRICHLOROBUTADIENES - A NEW ROUTETO CARBYNES

Authors
VOINTSEVA II GILMAN LM KUDRYAVTSEV YP EVSYUKOV SE PESIN LA GRIBOV IV MOSKVINA NA KHVOSTOV VV
Citation
Ii. Vointseva et al., CHEMICAL DEHYDROCHLORINATION OF POLYTRICHLOROBUTADIENES - A NEW ROUTETO CARBYNES, European Polymer Journal, 32(1), 1996, pp. 61-68
Citations number
26
Categorie Soggetti
Polymer Sciences
Journal title
European Polymer Journal → ACNP
ISSN journal
00143057
Volume
32
Issue
1
Year of publication
1996
Pages
61 - 68
Database
ISI
SICI code
0014-3057(1996)32:1<61:CDOP-A>2.0.ZU;2-V
Abstract
The chemical dehydrochlorination of polytrichlorobutadiene isomers, vi z. poly(I,1,2-trichlorobutadiene) and poly(1,2,3-trichlorobutadiene) h as been studied as a possible route to carbyne. The structure of the r eaction products has been studied by IR, XPS, and Auger electron spect roscopy. The dehydrochlorination of poly(1,1,2- and 1,2,3-trichlorobut adiene) has been shown to result in the formation of the polyyne and c umulene forms of carbyne, respectively.