A. Kurokawa et S. Ichimura, X-RAY PHOTOELECTRON-SPECTROSCOPY (XPS) ANALYSIS OF OXIDE FORMATION ONSILICON WITH HIGH-PURITY OZONE, JPN J A P 2, 34(12A), 1995, pp. 1606-1608
Initial oxide formation on a Si(111) surface with high-purity ozone (m
ore than 80% ozone concentration at the sample position) is investigat
ed by X-ray photoelectron spectroscopy (XPS). The suboxide formed by o
xidation is characterized from Si-2p spectra. From the comparison of t
he suboxides formed with ozone and oxygen exposures, it is clear that
ozone forms less suboxide than oxygen. Ozone oxidizes a monohydride Si
surface, which oxygen does not oxidize appreciably.