Yw. Ho et Ij. Wang, HETEROCYCLIC MONOAZO DYES DERIVED FROM 3-CYANO-2(1H)-PYRIDINETHIONE .2. TUTED-PYRAZOL-1-YL]CARBONYL]-THIENO[2,3-B]PYRIDINE DERIVATIVES, Dyes and pigments, 29(4), 1995, pp. 295-304
Acetylacetone and malononitrile were coupled with diazotised arylamine
s to give arylazoacetylacetones and arylazomalononitriles; these when
refluxed with 3-amino-4,6-dimethyl-2-thieno[2,3-b]pyridine carbohydraz
ide in the presence of glacial acetic acid yielded the corresponding r
bonyl]-3-amino-4,6-dimethyl-thieno[2,3-b]pyridine dyes. The dyes were
applied to polyester and polyamide fibres, and their spectral and fast
ness properties measured.