SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURE OF TRIS(1,10-PHENANTHROLINE)NICKEL(II) PERCHLORATE HEMIHYDRATE

Authors
ABDELRAHMAN L BATTAGLIA LP RIZZOLI C SGARABOTTO P
Citation
L. Abdelrahman et al., SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURE OF TRIS(1,10-PHENANTHROLINE)NICKEL(II) PERCHLORATE HEMIHYDRATE, Journal of chemical crystallography, 25(10), 1995, pp. 629-632
Citations number
13
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
25
Issue
10
Year of publication
1995
Pages
629 - 632
Database
ISI
SICI code
1074-1542(1995)25:10<629:SCAXCO>2.0.ZU;2-2
Abstract
The title compound was synthesized and characterized by conventional m ethods and its X-ray crystal structure was determined. The complex cry stallizes in the monoclinic space group C2/c with eight formula units in a cell of dimensions: a = 36.714(4), b = 15.746(2), c = 12.337(2) A ngstrom; beta = 102.9(1)degrees. The structure is built up by alternat e layers of octahedral [Ni(phen)(3)](2+) cations and perchlorate anion s with water molecules which run in the direction of the a axis nearly parallel to the be plane.