Yj. Jiang et al., MOLECULAR-STRUCTURE OF [CPRU(PPH(3))(2)(C6H11SH)]BF4-CENTER-DOT-CH2CL2, Journal of chemical crystallography, 25(10), 1995, pp. 653-656
The structure of the [CpRu(PPh(3))(2)(C6H11SH)]BF4 . CH2Cl2 complex wa
s determined by X-ray diffraction techniques: triclinic space group P
(1) over bar, a = 12.567(1), b = 13.409(1), c = 14.733(1) Angstrom, al
pha = 95.380(7), beta = 111.041(7), gamma = 96.454(8)degrees, V = 2278
.5(4) Angstrom(3), Z = 2, R = 0.056, R(w) = 0.088. The Ru is attached
to two triphenylphosphine ligands, a cyclopentadienyl and the S atom o
f the cyclohexylthiol. The Ru-S distance is 2.389(2) Angstrom and the
S-H distance is 1.23 Angstrom.