MOLECULAR-STRUCTURE OF [CPRU(PPH(3))(2)(C6H11SH)]BF4-CENTER-DOT-CH2CL2

Authors
JIANG YJ DRAGANJAC M CORDES AW
Citation
Yj. Jiang et al., MOLECULAR-STRUCTURE OF [CPRU(PPH(3))(2)(C6H11SH)]BF4-CENTER-DOT-CH2CL2, Journal of chemical crystallography, 25(10), 1995, pp. 653-656
Citations number
13
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
25
Issue
10
Year of publication
1995
Pages
653 - 656
Database
ISI
SICI code
1074-1542(1995)25:10<653:MO[>2.0.ZU;2-I
Abstract
The structure of the [CpRu(PPh(3))(2)(C6H11SH)]BF4 . CH2Cl2 complex wa s determined by X-ray diffraction techniques: triclinic space group P (1) over bar, a = 12.567(1), b = 13.409(1), c = 14.733(1) Angstrom, al pha = 95.380(7), beta = 111.041(7), gamma = 96.454(8)degrees, V = 2278 .5(4) Angstrom(3), Z = 2, R = 0.056, R(w) = 0.088. The Ru is attached to two triphenylphosphine ligands, a cyclopentadienyl and the S atom o f the cyclohexylthiol. The Ru-S distance is 2.389(2) Angstrom and the S-H distance is 1.23 Angstrom.