COORDINATIVELY SATURATED PT(II) COMPLEXES AS POTENTIAL PRECURSORS OF ORGANOMETALLIC POLYMERS

Authors
GIORDANO F PANUNZI B ROVIELLO A RUFFO F
Citation
F. Giordano et al., COORDINATIVELY SATURATED PT(II) COMPLEXES AS POTENTIAL PRECURSORS OF ORGANOMETALLIC POLYMERS, Inorganica Chimica Acta, 239(1-2), 1995, pp. 61-66
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
239
Issue
1-2
Year of publication
1995
Pages
61 - 66
Database
ISI
SICI code
0020-1693(1995)239:1-2<61:CSPCAP>2.0.ZU;2-X
Abstract
The synthesis of stable Pt(II) coordinatively saturated derivatives su itable as precursors of organometallic polymers is described. Compound s of the type [PtX(2)(dmphen) (olefin)] (X = CN, SCN; dmphen = 2,9-Me( 2)-1,10-phenanthroline) are obtained by oxidative addition to Pt(0) sp ecies. The unprecedent fission of activated carbon-carbon bonds to giv e 18 e(-) Pt(II) species is described. The solid state structure of [P t(SCN)(2)(dmphen) (dimethylmaleate)] has been determined by X-ray crys tallography. Vinyl monomers [PtCl(RCH=CH2)-(dmphen)(dimethylmaleate)] (R = CO2, CH2CO2) have also been obtained.