INFRARED-EMISSION SPECTRA FROM CRYOGENIC PROTON-IRRADIATED HELIUM GAS

Citation
Dw. Tokaryk et al., INFRARED-EMISSION SPECTRA FROM CRYOGENIC PROTON-IRRADIATED HELIUM GAS, The Journal of chemical physics, 103(24), 1995, pp. 10439-10444
Citations number
15
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
103
Issue
24
Year of publication
1995
Pages
10439 - 10444
Database
ISI
SICI code
0021-9606(1995)103:24<10439:ISFCPH>2.0.ZU;2-Q
Abstract
Spectra from proton-beam irradiated helium gas, near 4.2 K, have been examined in the near infrared spectral region using a sensitive photom ultiplier-grating spectrometer combination (750-1000 nm) and a Fourier transform infrared spectrometer with an InGaAs detector (800-1800 nm) . Most of the observed features can be assigned to known He, transitio ns, and two bands, not previously observed (d (3) Sigma(u)(+) (nu = 4) --> c (3) Sigma(g)(+) (nu = 3, 4)) have been identified and analyzed. Some of the unidentified spectra have qualitative similarity to a set of visible emission lines tentatively assigned to an excimer-dimer (i .e., He-4, two He-2 excimers weakly bound together). These features, u nlike the normal He-2 spectra, demonstrate pronounced dependence on bo th the pressure and temperature of the sample. A comparison of the int ensities of the singlet and triplet D(d) --> C(c) transitions to the s inglet and triplet C(c) --> A(a) transitions is made. (C) 1995 America n Institute of Physics.