Dw. Tokaryk et al., INFRARED-EMISSION SPECTRA FROM CRYOGENIC PROTON-IRRADIATED HELIUM GAS, The Journal of chemical physics, 103(24), 1995, pp. 10439-10444
Spectra from proton-beam irradiated helium gas, near 4.2 K, have been
examined in the near infrared spectral region using a sensitive photom
ultiplier-grating spectrometer combination (750-1000 nm) and a Fourier
transform infrared spectrometer with an InGaAs detector (800-1800 nm)
. Most of the observed features can be assigned to known He, transitio
ns, and two bands, not previously observed (d (3) Sigma(u)(+) (nu = 4)
--> c (3) Sigma(g)(+) (nu = 3, 4)) have been identified and analyzed.
Some of the unidentified spectra have qualitative similarity to a set
of visible emission lines tentatively assigned to an excimer-dimer (i
.e., He-4, two He-2 excimers weakly bound together). These features, u
nlike the normal He-2 spectra, demonstrate pronounced dependence on bo
th the pressure and temperature of the sample. A comparison of the int
ensities of the singlet and triplet D(d) --> C(c) transitions to the s
inglet and triplet C(c) --> A(a) transitions is made. (C) 1995 America
n Institute of Physics.