Ak. Chakraborty et Ei. Shakhnovich, PHASE-BEHAVIOR OF RANDOM COPOLYMERS IN QUENCHED RANDOM-MEDIA, The Journal of chemical physics, 103(24), 1995, pp. 10751-10763
In this paper, we consider the behavior of random heteropolymers in a
quenched disordered medium. We develop a field theory and obtain a mea
n-field solution that allows for replica symmetry breaking. The presen
ce of an external disorder leads to the formation of compact states; a
homopolymeric effect. We compute the phase diagram for two classes of
problems. First, we consider the situation wherein the bare heteropol
ymer prefers like segments to segregate, and second, we examine cases
where the bare heteropolymer prefers unlike segments to mix. For the f
irst class of systems, we find a phase diagram characterized by a repl
ica symmetry broken phase that exists below a particular temperature.
This temperature grows with the strength of the external disorder. In
the second class of situations, the phase diagram is much richer. Here
we find two replica symmetry broken phases with different patterns se
parated by a reentrant phase. The reentrant phase and one of the two r
eplica symmetry broken phases are induced by interactions with the ext
ernal disorder. The dependence of the location of the phase boundaries
on the strength of the external disorder are elucidated. We discuss o
ur results from a physical standpoint, and note the testable experimen
tal consequences of our findings. (C) 1995 American Institute of Physi
cs.