CHLOROTROPIC REARRANGEMENTS OF AN ALPHA-SULFANYL-ALPHA-SULFONYLALKANESULFENYL CHLORIDE TO AN ALPHA-CHLOROALKYL DISULFIDE AND AN S-(ALPHA-CHLOROALKYL) THIOSULFONATE

Citation
I. Elsayed et al., CHLOROTROPIC REARRANGEMENTS OF AN ALPHA-SULFANYL-ALPHA-SULFONYLALKANESULFENYL CHLORIDE TO AN ALPHA-CHLOROALKYL DISULFIDE AND AN S-(ALPHA-CHLOROALKYL) THIOSULFONATE, Journal of the Chemical Society. Perkin transactions. I, (10), 1994, pp. 1251-1252
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
10
Year of publication
1994
Pages
1251 - 1252
Database
ISI
SICI code
0300-922X(1994):10<1251:CROAA>2.0.ZU;2-4
Abstract
(1-Adamantylsulfonyl) (pentachlorophenylsulfanyl)chloromethane chlorid e. 3, dan undergo two quantitative chlorotropic rearrangements, the mo re facile one leading to (1-adamantylsulfonyl)dichloromethyl pentachlo rophenyl disulfide, 4, the less facile one forming sulfanyl)dichlorome thyl]adamantane-1-thiosulfonate 5.