CHLOROTROPIC REARRANGEMENTS OF AN ALPHA-SULFANYL-ALPHA-SULFONYLALKANESULFENYL CHLORIDE TO AN ALPHA-CHLOROALKYL DISULFIDE AND AN S-(ALPHA-CHLOROALKYL) THIOSULFONATE
I. Elsayed et al., CHLOROTROPIC REARRANGEMENTS OF AN ALPHA-SULFANYL-ALPHA-SULFONYLALKANESULFENYL CHLORIDE TO AN ALPHA-CHLOROALKYL DISULFIDE AND AN S-(ALPHA-CHLOROALKYL) THIOSULFONATE, Journal of the Chemical Society. Perkin transactions. I, (10), 1994, pp. 1251-1252
(1-Adamantylsulfonyl) (pentachlorophenylsulfanyl)chloromethane chlorid
e. 3, dan undergo two quantitative chlorotropic rearrangements, the mo
re facile one leading to (1-adamantylsulfonyl)dichloromethyl pentachlo
rophenyl disulfide, 4, the less facile one forming sulfanyl)dichlorome
thyl]adamantane-1-thiosulfonate 5.