PHASE-SEPARATION IN LIQUID-CRYSTALLINE COPOLYMER POLY(METHYL METHACRYLATE) BLENDS/

Citation
Ae. Nesterov et al., PHASE-SEPARATION IN LIQUID-CRYSTALLINE COPOLYMER POLY(METHYL METHACRYLATE) BLENDS/, Collection of Czechoslovak Chemical Communications, 60(11), 1995, pp. 1869-1874
Citations number
21
Categorie Soggetti
Chemistry
ISSN journal
00100765
Volume
60
Issue
11
Year of publication
1995
Pages
1869 - 1874
Database
ISI
SICI code
0010-0765(1995)60:11<1869:PILCPM>2.0.ZU;2-Q
Abstract
The phase separation in the blends of poly(methyl methacrylate) and li quid-crystalline polymer (copolymer of ethylene terephthalate and p-hy droxybenzoic acid) has been studied by the light scattering method and the cloud point curves have been obtained. Simultaneously some morpho logical features of the blends have been observed. It was found that t he initial blends are in the state of forced compatibility and that th ermally induced phase separation occurs by the mechanism of spinodal d ecomposition but presumably in the non-linear regime.