COMPARISON OF THE FT RAMAN-SPECTRA OF INORGANIC TETRAHEDRAL IONS OVERTHE TEMPERATURE-RANGE 77 TO 473 K

Authors
POPE SJA WEST YD
Citation
Sja. Pope et Yd. West, COMPARISON OF THE FT RAMAN-SPECTRA OF INORGANIC TETRAHEDRAL IONS OVERTHE TEMPERATURE-RANGE 77 TO 473 K, SPECT ACT A, 51(12), 1995, pp. 2027-2037
Citations number
35
Categorie Soggetti
Spectroscopy
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY → ACNP
ISSN journal
13861425
Volume
51
Issue
12
Year of publication
1995
Pages
2027 - 2037
Database
ISI
SICI code
1386-1425(1995)51:12<2027:COTFRO>2.0.ZU;2-0
Abstract
The vibrational spectra recorded over a wide temperature range (77-473 K) of a number of inorganic transition metal salts containing tetraox yanions in both solution and crystal phases are reported. All modes in these cases are Raman active and the bands predicted by site-symmetry analysis are observed. Only bands assigned as nu(3) and nu(1) are fou nd to be temperature dependent. The significance of this is discussed.