CONCENTRATION CHANGES IN THE NEAR-ELECTRODE LAYER DURING CATHODIC POLARIZATION OF THE OXYGEN-ELECTRODE IN HYDROXIDE MELTS

Authors
TKALENKO DA KUDRYA SA SUNEGIN GP TKALENKO MD
Citation
Da. Tkalenko et al., CONCENTRATION CHANGES IN THE NEAR-ELECTRODE LAYER DURING CATHODIC POLARIZATION OF THE OXYGEN-ELECTRODE IN HYDROXIDE MELTS, Russian journal of electrochemistry, 31(11), 1995, pp. 1207-1210
Citations number
5
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
31
Issue
11
Year of publication
1995
Pages
1207 - 1210
Database
ISI
SICI code
1023-1935(1995)31:11<1207:CCITNL>2.0.ZU;2-4
Abstract
A mathematical model describing mass and charge transfer and chemical reactions during cathodic polarization of the oxygen electrode in molt en potassium hydroxide is developed and examined. The concentration pr ofiles of reagents and reaction products are calculated for different polarization modes. An increase in basicity of the near-electrode laye r is quantitatively evaluated.