SYNTHESIS OF STABLE HYDROPEROXIDES OF SULTAMS BY OXIDATION OF ISOTHIAZOLIUM SALTS

Authors
SCHULZE B KIRRBACH S ILLGEN K FUHRMANN P
Citation
B. Schulze et al., SYNTHESIS OF STABLE HYDROPEROXIDES OF SULTAMS BY OXIDATION OF ISOTHIAZOLIUM SALTS, Tetrahedron, 52(3), 1996, pp. 783-790
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
3
Year of publication
1996
Pages
783 - 790
Database
ISI
SICI code
0040-4020(1996)52:3<783:SOSHOS>2.0.ZU;2-H
Abstract
In this paper the first synthesis of stable 3-hydroperoxy-sultams 3a-d as well as the corresponding isothiazol-3(2H)-one I,l-dioxides 8a-e b y oxidation of isothiazolium salts 6a-e is reported. The 3-hydroxy-sul tams 7b-d are obtained by reduction of hydroperoxides 3b-d.