To understand the exceedingly rich structure of the quantum excited st
ates in nuclei, the importance of exploring the complex structure of t
he time-dependent Hartree-Fock (TDHF) manifold is discussed. It is sho
wn that various ideas developed in the general theory of non-linear dy
namics (e.g., non-linear resonance, elliptic and hyperbolic fixed poin
ts, order-to-chaos transition, etc.,) play a decisive role in obtainin
g analytic information on the quantum excited states, provided that th
e corresponding TDHF manifold has a simple potential energy surface (P
ES) with only one minimum. When the TDHF manifold has a PES with more
than two local minima, one is involved into an important problem relat
ed with adiabatic versus diabatic collective potentials. The adiabatic
collective potential is usually obtained when one numerically solves
the constrained Hartree-Fock (CHF) equation within a constraining coor
dinate space, which has a limited number of degrees of freedom. To exp
lore the dynamical relation between the adiabatic and diabatic single-
particle states, one has to analyze the CHF method within the full TDH
F manifold, which includes the constraint coordinate space. It turns o
ut that the solutions of the CHF equation give many differentiable sur
faces in the TDHF manifold. By using the differentiable property of th
e CHF solutions in the TDHF manifold, a new method for reaching variou
s HF points is discussed.