SYNTHESIS AND BIOMIMETIC REARRANGEMENT OF A CHIRAL DITERPENE DIOXIDE

Authors
LINDEL T FRANCK B
Citation
T. Lindel et B. Franck, SYNTHESIS AND BIOMIMETIC REARRANGEMENT OF A CHIRAL DITERPENE DIOXIDE, Tetrahedron letters, 36(52), 1995, pp. 9465-9468
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
52
Year of publication
1995
Pages
9465 - 9468
Database
ISI
SICI code
0040-4039(1995)36:52<9465:SABROA>2.0.ZU;2-Q
Abstract
As pan of a biomimetic approach towards the marine triterpene teurilen e (2), the synthesis of the chiral diepoxide 3 is described Aiming at the synthesis of the squalene tetraepoxide 1, double Sharpless epoxida tion led to the intermediate bisglycidic alcohol 7 being subject to a stereochemical analysis.