A FURTHER BREAKTHROUGH IN BIPHASIC, RHODIUM-CATALYZED HYDROFORMYLATION - THE USE OF PER(2,6-DI-O-METHYL)-BETA-CYCLODEXTRIN AS INVERSE PHASE-TRANSFER CATALYST

Authors
MONFLIER E TILLOY S FREMY G CASTANET Y MORTREUX A
Citation
E. Monflier et al., A FURTHER BREAKTHROUGH IN BIPHASIC, RHODIUM-CATALYZED HYDROFORMYLATION - THE USE OF PER(2,6-DI-O-METHYL)-BETA-CYCLODEXTRIN AS INVERSE PHASE-TRANSFER CATALYST, Tetrahedron letters, 36(52), 1995, pp. 9481-9484
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
52
Year of publication
1995
Pages
9481 - 9484
Database
ISI
SICI code
0040-4039(1995)36:52<9481:AFBIBR>2.0.ZU;2-G
Abstract
Solvent free biphasic hydroformylation of various water-insoluble term inal olefins can be achieved in high yields and selectivities by using a water-soluble rhodium/triphenylphosphine trisulfonate catalyst and per(2,6-di-o-methyl)-beta-cyclodextrin as inverse phase transfer catal yst. The catalytic activities were up to ten times higher than those o bserved without per(2,6-di-o-methyl)-beta-cyclodextrin.