SOLVENT-CONTROLLED ADDITION OF ALKYNYLTINS OR ALLYLIC TINS TO ALDEHYDES CATALYZED BY INDIUM TRICHLORIDE

Authors
YASUDA M MIYAI T SHIBATA I BABA A NOMURA R MATSUDA H
Citation
M. Yasuda et al., SOLVENT-CONTROLLED ADDITION OF ALKYNYLTINS OR ALLYLIC TINS TO ALDEHYDES CATALYZED BY INDIUM TRICHLORIDE, Tetrahedron letters, 36(52), 1995, pp. 9497-9500
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
52
Year of publication
1995
Pages
9497 - 9500
Database
ISI
SICI code
0040-4039(1995)36:52<9497:SAOAOA>2.0.ZU;2-G
Abstract
Indium trichloride promoted catalytically. the addition of alkynyltins or allylic tins to aldehydes in two ways: transmetallation with the t in compounds and activation of aldehydes as a Lewis acid. The stereoch emical outcome in the addition of cinnamyltributyltin to an aldehyde s trongly indicates that control of the process can be achieved simply b y the choice of solvent acetonitrile or dichloromethane.