FORMATION OF HYDROXAMIC ACIDS PROMOTED BY METAL-IONS - INTERACTION OFALDEHYDE CARBONYL GROUP WITH C-NITROSO GROUP IN THE PRESENCE OF FERRIC IONS

Authors
URSIC S NIGOVIC B VRCEK V PILEPIC V
Citation
S. Ursic et al., FORMATION OF HYDROXAMIC ACIDS PROMOTED BY METAL-IONS - INTERACTION OFALDEHYDE CARBONYL GROUP WITH C-NITROSO GROUP IN THE PRESENCE OF FERRIC IONS, Tetrahedron letters, 36(52), 1995, pp. 9547-9550
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
52
Year of publication
1995
Pages
9547 - 9550
Database
ISI
SICI code
0040-4039(1995)36:52<9547:FOHAPB>2.0.ZU;2-4
Abstract
Formation of N-phenyl substituted hydroxamic acids in the reaction of formaldehyde with substituted nitrosobenzene is strongly catalysed by Fe3+ ions, which stabilize the transition state for the rate-controlli ng proton transfer from the carbon of nitrosocarbinolic cation interme diate leading to the product, hydroxamic acid.